This textbook offers the most important issues related to the application of surface acoustic waves (SAW) in gas sensors. The essence of operation, general theoretical models, research methodology, bi-layer and light-activated sensor structures are presented in an understandable way. The original results of the sensor properties studies of selected single, bilayered structures, as well as prototype multi-layer structures and for the first time, a detailed theoretical description of the acoustoelectrical effect for bilayer sensor structures were presented. Most attention was paid to semiconductor-metal bilayer structures, such as phthalocyanine-palladium or tungsten oxide-palladium, as they are the most promising in terms of practical applications in SAW hydrogen sensors. The prospects of applications and further research taking into account the latest solutions based on light-activated photoconductive polymer structures are also indicated.